Materials Performance

DEC 2016

Materials Performance is the world's most widely circulated magazine dedicated to corrosion prevention and control. MP provides information about the latest corrosion control technologies and practical applications for every industry and environment.

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11 NACE INTERNATIONAL: VOL. 55, NO. 12 MATERIALS PERFORMANCE DECEMBER 2016 Continued on page 12 Adhesion Testing Q: I am looking for your considered opinion on the following: Is fair adhesion for the knife/tape tests accept- able for a newly applied inorganic zinc (IOZ)/epoxy/urethane coating system in terms of expected service life or perfor- mance? A: e problem with the knife test is in the skill and experience of the person conducting the test. It is highly subjective and you can get various degrees of results. e tape test is a little more objective, but it is still not a good tool for predicting service life of a newly applied IOZ/epoxy/urethane coating system. Several other factors have to be considered such as the plane of detach- ment within the coating system, the ty pe of detachment (flakes or peels), etc. A: My only comment would be is if you get a number less than a three you probably have a problem. If you get a four or five you probably do not have an adhesion problem but that does not necessarily correlate to the coating life cycle. A value less than three would certainly warrant concern and further evaluation of the coating system. Likewise with tensile adhesion. A low number might indicate a problem but a high number does not necessarily mean the coating system will achieve its full life cycle. In general, lower than expected numbers with either test indicate "possi- ble" problems. High numbers don't tell you as much. A: An evaluation of the system that you outlined resulting in any thing less than "very good " would seem to indicate that a more sophisti- cated evaluation should be performed. e time to deal with any skepticism is prior to warranty expiration, while the information on the project is still somewhat fresh. A: I would suggest asking the coating manufacturer if it will warrant its product with those test results and maybe also what that warranty would include. Old Lining Evaluation Q: We need to evaluate a two-coat, 30- to 35-mil (0.8- to 0.9-mm) glass f lake-f illed vinyl ester tank lining with close to 17 years of service. Visually, the lining appears to be intact. Several pull tests resulted in a combination of adhesive and cohesive failures between coats and in the topcoat. We discovered that a hold primer was used after the f irst coat of vinyl ester. None of the pull tests separated below this hold primer layer. The tank has held a variety of chemicals, oils, sludge, and solids (simultaneously).

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