Materials Performance

NOV 2017

Materials Performance is the world's most widely circulated magazine dedicated to corrosion prevention and control. MP provides information about the latest corrosion control technologies and practical applications for every industry and environment.

Issue link: http://mp.epubxp.com/i/889936

Contents of this Issue

Navigation

Page 15 of 84

13 NACE INTERNATIONAL: VOL. 56, NO. 11 MATERIALS PERFORMANCE NOVEMBER 2017 SEE CORRPRO. Successfully loading deep anode wells is an art and will depend a lot on the geolog y and drilling method. A good, experienced anode well driller is key. A: Refer to NACE SP0572, "Design, Installation, Operation, and Maintenance of Impressed Current Deep Anode Beds." Pouring is not the best way to fill in the active area. A water/coke mix is advisable but not always economical if your anode bed is not very deep. Aluminum Anodes Q: Could you tell me in what resis- tivities aluminum anodes work eff iciently? Is there any standard stipulat- ing the water resistivity values? For example, NACE standards state that zinc with g y psum and bentonite backf ill are used in soils having relatively low resis- tivity (<2,000 Ω-cm). A: Normally, aluminum anodes are used only in seawater, which has a resistivity of ~25 Ω-cm. Even then they have a small amount of alloying to prevent passivation. A luminum anodes generally require chloride ions in the electroly te to function properly. As the quantity of chloride ions decreases below normal seawater concentrations (3.5%, or 35,000 ppm), the current capacity of the anode decreases, and the anode potential becomes more noble. Refer to the NACE Corrosion Engineer's Reference Book , ird Edition, in the chapter "Design Criteria for Offshore Cathodic Protection Systems." A: A luminum alloy anodes require the presence of chloride ions to prevent passivation. Obviously, an environment with a sufficient amount of chlorides to operate the anodes will have a low resistivity, but resistivity is not the key factor. We could have a medium with low resistivity, but if there are no chlorides, the anodes will not work. According to S.N. Smith, et al. (MP 17, 3 [1978], p. 32), the minimum required chloride concentration in waters is ~1,800 to 2,000 ppm. C.F. Schrieber and R.N. Murray (MP 27, 7 [1988], p. 70) found that A l-Zn-In-Si anodes in brackish waters >12% seawater strength exhibit current capacities (A-h/kg) equal to those observed in full- strength seawater. At saline strength <12%, severe capacity scatter is observed. Anode potentials show acceptable values 9–1.07 to –1.10 V vs. silver/silver chloride (Ag/AgCl) through 33% strength seawater. At ~20% seawater strength and less, noticeable potential variance will occur. Continued f rom page 11 NACE International offers more than 400 books covering every aspect of corrosion control in all industries. For more information, visit the NACE Store at www.nace.org.

Articles in this issue

Links on this page

Archives of this issue

view archives of Materials Performance - NOV 2017