Materials Performance

AUG 2017

Materials Performance is the world's most widely circulated magazine dedicated to corrosion prevention and control. MP provides information about the latest corrosion control technologies and practical applications for every industry and environment.

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34 AUGUST 2017 MATERIALS PERFORMANCE NACE INTERNATIONAL: VOL. 56, NO. 8 CATHODIC PROTECTION N In this work, linear sweep voltammetry and zero resistance ammeter meth- ods using rotating disk electrodes were utilized to determine and char- acterize the galvanic interaction be- tween mineral particles and AISI 1020 carbon steel immersed in seawater for a combination of exposed areas and electrode rotating rates. Galvanic cur- rent and potential values obtained from both methods were compatible. The experimental galvanic corrosion density values, which are much larger than those of non-galvanic corrosion, reveal a serious threat to pipelines and infrastructure that handle concen- trate suspensions during mineral pro- cessing operations. North ern Chile is an extrem ely arid region containing large deposits of copper and other minerals. Under these condi- tions, recent industrial expansion has been made possible by using seawater in mineral processing. This subjects mining equip- ment and piping to var ying degrees of corrosion depending upon the nature of the materials and operational conditions. In this work, electrochemical methods based on linear sweep voltammetry (LSV ) and zero resistance ammeter (ZRA) techniques employing rotating disk electrodes (RDE) were used to measure and characterize carbon steel (CS) corrosion produced from galvanic C S-min eral c oupl e s w ith th e Galvanic Interaction Between Carbon Steel and Copper Concentrate Genny Leinenweber and Luis Cá C eres V, Universidad de Antofagasta, Antofagasta, Chile mineral in the form of copper concentrate from flotation cells. Experimental Procedures Materials and Reagents Mineral A copper concentrate mineral sample from a local mining company was washed with distilled water and acetone to remove f lotation additives added during the min- eral processing. This sample, with a parti- cle size distribution value of D50 in the range of 2 to 35 μm, was characterized by x-ray diffraction (Table 1). Metal Specimen The working electrode, AISI 1020 CS RDE (SRDE), was comprised of a 4.2-mm diameter rod inserted into a Teflon † cylin- der attached to a rotating shaft (BASi † model RDE-2 rotator system). Wax-Graphite Electrodes Electrochemical tests with copper con- centrate mineral particles were made using a wax-graphite RDE (WRDE). 1-2 Seawater Two seawater samples were taken from a coastal site in Antofagasta, Chile, and then filtered through a membrane filter, with a 0.2- μ m pore size, to remove sus- pended particles. † Trade name.

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