Materials Performance

OCT 2017

Materials Performance is the world's most widely circulated magazine dedicated to corrosion prevention and control. MP provides information about the latest corrosion control technologies and practical applications for every industry and environment.

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39 NACE INTERNATIONAL: VOL. 56, NO. 10 MATERIALS PERFORMANCE OCTOBER 2017 outlined in ASTM D4940. 12 Figure 5 shows measured test levels for chlorides, sulfates, and nitrates. This represents a small but meaning ful spot check of commercial abrasives used commonly for surface preparation. Condi- tions of pressure, particle size, friability, and hardness can all contribute to transfer levels. The results in Table 1 can be com- pared with those in Table 2, which were from small samples of various commer- cially used abrasives received two months prior and were analyzed for chloride, sul- fate, and nitrate contamination with the s a m e f i e l d t e st k i t m e t h o d o u t l i n e d previously. The test results in Table 1 can be com- pared with prior published tests using doped abrasives to certain chloride con- tamination levels to determine transfer rates and in order to provide some initial guidance on limits, which may be consid- ered "safe" for not transferring soluble anionic salt species to the substrate. These include: FIGURE 1 Extraction for chloride, sulfate, and nitrate detection. FIGURE 3 Abrasive blasting of test panels. FIGURE 2 Sample collection: (a) collecting measured sample; (b) transferring sample to extraction container; and (c) autovial sample filtration. FIGURE 4 Combined "CSN" and "A" kits. FIGURE 5 Test measurement levels: (a) chloride, (b) sulfates, and (c) nitrates. • Research conducted at Transport SA (Adelaide, South Australia) calcu- lated a limit of ~20 mg/kg (ppm) of chloride before transfer to blasted substrates occurs. 13 • A European Commission report was i n t e r pre t e d a n d e xtra p o l a t e d t o ref lect a level <20 mg/kg (ppm) of chloride as a limit before transfer occurred. 14 A f u r t h e r d a t a p o i n t i s t h e l i m i t ref lected in the 11127 series of ISO stan- dards, which specify a limit of 25 mg/kg (ppm) of chloride from various abrasives. No details were found to validate the basis for this data.

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